Bravo!!.... this is wonderful!.... BTW... you have a lot of time on your hands LOL :P

Great choices for images they all call to mind great moments.
Mal: "It doesn't have to go this way."/Serenity
Book: "Thought the outfit gave it away."/Serenity
Jayne: "Little Kaylee here just wishes you was a gynecologist."/Serenity
Wash: "Everything looks good from here... Yes... Yes... This is a fertile land..."/Serenity
Kaylee: "Your gonna come with us."(love that line)/Serenity
Inara: Flying in her shuttle
River: "It's just an object, doesn't mean what you think."/Objects in Space
Simon and Zoe must be publicity photos because i don't recognize them instantly as being associated with any particular scene.
Beautiful job.